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CHIEF PROCESSES IN LEATHER MANUFACTURE 1) Pre-tannage
(beam house operations)
The purpose of these operations is to increase the amount of water in the hide, to the amount close to that of the "living" hide, remove foreign bodies and loosen structure. This loosening makes it easier for the tanning agents, fats, dyestuffs and other substances, to penetrate into the hide. In the beam house the non collagenous proteins are removed from the hide, so is its epidermis, hair and globular proteins, melamins, components of cell walls, while collagen fiber skeleton remains practically untouched. 2) Tannage
(tannery operations)
3) After tannage
(finishing operations)
There are many variants on this simple outline. All these processes, their choice and control which determine the quality of the leather made form the basis of Leather Technology. In almost all stages, substances are moving either into or out of the skin or hide. Process of wetting back, conditioning and drying involve mainly the movement of water. During liming, deliming, pickling and neutralizing salts, acids and alkali are involved. In tanning, dyeing and fatliquoring, various chemicals move into the skin, while in liming and bating, unwanted materials migrate to the surface and pass into the surrounding liquor. There is a large variation in the pH . The pH of processes:
In a wet rawhide, the peptide groups and particularly
acid and basic groups hydrate. Water molecules are attached to and
bound to these groups. The more water attracted to the protein molecule,
the more it becomes separated from the adjacent molecule, so that the molecules
are pushed apart and the skin is said to
swell. By increasing the ionization of either the acid or
basic groups by the addition of alkali or acid respectively,
the attraction for water is increased and the skin
swells or "plumps" more.
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