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PARAFFIN DEGREASING
Paraffin degreasing:excessive
amounts of grease may interfere with uniform penetration of tan or dye,
show difficulties or greasy patches in the finished leather.
Degreasing is particularly important before chrome
tannage, where chrome salts can react with some greases to produce chrome
soaps.
In the case of paraffin greasing, well drained pickled skins are drummed
with half their weight of paraffin(for 1-2 hrs). The
paraffin loosens the grease.A small amount of wetting
agent may be added to the paraffin( 5 % non ionic wetting agent).At
the end the greasy paraffin is drained off. A considerable amount is held
by the skin and may be removed by squeezing process(expensive). It is more
usuall to wash the skins in a drum with a 5 % salt solution at 27 0C
for approx.30 mins. Salt solution must be used as water alone would result
in acid swelling. This washing is repeated until wash solution remains
clear. Many skin greases or fats are semi-solid cold
(15 0C) and even at the maximum temperature of 38 0C
permissible on raw skins to avoid heat damage or shrinkages, such fats
or greases are still only melted to a viscous pasty mass (particularly
if they contain water in oil emulsion). By
light pretannage of the skins with 1 % formalin in short float, enough
to raise shrinkage temperature by 10 0C, the skins can be safely
treated at temperature 45 0C when these pasty fats are quite
fluid and easily emulsified.
Dry degreasing process:
This is done on dry tanned leather and consist of treating the leather
with fat or grease solvents such as white spirits (inflammable)
or chlorinated hydrocarbons (non-inflammable
but toxic) such as trichloroethylene or perchloroethylene.
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